The 1% is probably degraded peptide or peptide fragments, nothing to worry about. However that total 100% refers to the target peptide, there is other stuff in the vial that isn’t included in a purity test. So if you had 1mg of perfectly pure tirz in a base of 100mg of cyanide, the test would show 100% purity because it isn’t looking for that cyanide.
Edit to add: the take home point is that these tests will help you know that the vendor sold you what they said they would, but it doesn’t mean it is pharma-safe. For that you need to spend pharma money. That’s the trade off we are making here, best to be clear-eyed about it.